Ms Pearce won 454 of the 728 votes cast in the NUS presidential election ballot, which took place at the organisation鈥檚 annual conference in Liverpool on 8 April.
NUS black students officer Aaron Kiely received 150 votes, University of London representative and self-declared 鈥渕ilitant trade unionist鈥 Daniel Cooper picked up 90 and Ukip鈥檚 youth secretary Jack Duffin just 18 votes.
Ms Pearce is the eighth woman president of the NUS and the first to come from a further education college in the post-1992 era.
In her keynote address to conference on 7 April, Ms Pearce said she wanted to create a 鈥渘ew deal for the next generation鈥 and put pressure on all political parties to improve opportunities for students.
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However, she appeared to back away from her organisation鈥檚 policy of targeting Liberal Democrat MPs who voted in 2010 in favour of increasing tuition fees.
More than 1,000 parliamentary candidates, including 400 from the Lib Dems and 200 from Labour, pledged not to increase tuition fees in 2010 and Ms Pearce said 鈥渨e have not forgotten who broke their promises鈥.
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But she did not want the NUS to simply focus on the 40 or so Lib Dem MPs who signed a pledge to oppose tuition fees hikes in 2010, but later voted in favour of them in 2012, saying she 鈥渄id not want to have a Tarantino-style revenge campaign鈥 against Lib Dems.
However, the conference later backed a motion which called for the NUS to 鈥渃ampaign against Nick Clegg and any MP who broke their pledge to students by publicly highlighting their broken promise鈥.
That motion would appear to step back from the more explicit vow to target senior Lib Dem MPs, including Nick Clegg, and mobilise student support against them when these politicians contest their seats at the 2015 general election.
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